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I would actually predict the bond to be relatively weak on account of the relatively large size of the si atom leading to a relatively long bond length and hence poor orbital overlap. While there are some other polymers that have better mechanical or thermal properties, i am not aware of any that have better chemical resistance. If you are using comparative bond strengths to determine if a reaction is favorable, you need to consider the bonds in the products as well as those in the reactants

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The article by gillespie argues you should avoid the phrase ionic character because ionic and covalent aren't mutually exclusive You can even do the finkelstein on aromatic rings if you add catalytic copper (i) iodide and a diamine to activate it. It's pretty clear from dipole moment in diatomic lif and quantum calculations that ~0.9 electrons are transferred